Torrefied Wood - Green Coal

Woody biomass  consists of hemicellulose , cellulose, lignins and extractants (chemicals absorbed  during the growing cycle through air and dirt, generally <3%).  During torrefaction the molecular structure of the wood is altered, enhancing some of the wood’s physical properties. 

Torrefaction   liberates water and  releases volatile organic compounds (VOC) through the devolitization of primarily the hemicelluloses and extractants. The lignins are loosened and have limited devolitization while the cellulose is nearly unimpacted at these temperatures.  As the hemicellulose,   which binds the cellulose,  is burned away,   the wood is unbound making it more brittle.   This increases the grindability of torrefied wood  and makes its  handling properties  more like coal.  This unbinding also releases the last of the water not stored at the cell level, leaving the wood hydrophobic.  This new nature allows the product to be stored outdoors without concern for exposure to water.  

 

 During the torrefaction process most  of the energy value of the wood is preserved  with the product losing  20-30% of its mass while retaining 90% of its energy.   The calorific  value of the wood increases to 9,500-11,500 Btu per pound.